Cerium(III) dihydroxidohexaoxidotetraborate chloride
نویسندگان
چکیده
The crystal structure of the title compound, Ce[B(4)O(6)(OH)(2)]Cl, is built from polyborate sheets parallel to the (001) plane. These sheets stack along the [001] direction and are linked by Ce atoms exhibiting an CeO(8)Cl(2) coordination sphere. O-H⋯O and O-H⋯Cl hydrogen bonds additionally stabilize the structural set-up. The polyborate sheet is made up of zigzag borate chains running along the [[Formula: see text]10] direction. These zigzag chains are inter-connected by shared O-vertices, resulting in a two-dimensional layer with nine-membered rings. All B and O atoms (except for the terminal OH atoms) lie in the nearly planar sheets of polyborates, leading to their isotropic atomic displacement parameters being significantly smaller than usual. This may be attributed to the fact that the atomic displacement parameters correlate not only with their atomic masses but with their coordination environments also.
منابع مشابه
Oxidation of Vicinal Diols by Cerium(IV) in Aqueous Acidic Media Catalyzed by Rhodium(III)
Potential of rhodium(III) chloride in catalyzing, in aqueous sulfuric acid medium, the oxidation of vicinal diols, and the kinetics of reaction of cerium(IV) with propane-1,2-diol and butane-2,3-diol catalyzed by rhodium(III) chloride was investigated. Data show that the reactions follow first order kinetics with respect to low cerium(IV) for lower concentrations, but a further increase in the ...
متن کاملA Simple and Sensitive Assay for Measuring Very Small Volumes of Microprinted Solutions
This study describes an extremely sensitive and simple assay to measure small volumes of solutions, <1 nL. The assay takes advantage of the Sandell-Kolthoff reaction in which yellow cerium(IV) is reduced to colorless cerium(III) in the presence of arsenic(III) and catalytic quantities of iodide ion. The reaction is linear with respect to the rate of Ce(IV) reduction and the quantity of I(-) pre...
متن کاملCerium(III)-catalyzed cascade cyclization: an efficient approach to functionalized pyrrolo[1,2-a]quinolines.
A general and practical route to the synthesis of multisubstituted pyrrolo[1,2-a]quinolines has been described from 2-alkylazaarenes and nitroolefins using cerium chloride as a catalyst via a tandem Michael addition, cyclization and aromatization. This protocol features readily available starting materials, operational simplicity and high regioselectivity to access multifunctionalized pyrrolo[1...
متن کاملApplication of cerium chloride to improve the acid resistance of dentine.
OBJECTIVE To investigate the effect of cerium chloride, cerium chloride/fluoride and fluoride application on calcium release during erosion of treated dentine. METHODS Forty dentine samples were prepared from human premolars and randomly assigned to four groups (1-4). Samples were treated twice a day for 5 days, 30s each, with the following solutions: group 1 placebo, group 2 fluoride (Elmex ...
متن کاملIncorporation Solvation With Cloud Point Extraction Method for Separation and Spectrophotometric Determination of Cerium (III) SHAWkET kADHIM JAWAD1, MOUSA OMRAN kADHIM and ALAA SALEH ALWAN
Through joined two sensitive methods solvation and cloud point extraction separated and determined micro amount of Ce(III) from aqueous solutions by using organic reagent 2,4-Dimethyl pentan-3-one (2,4-DMP) as extractant and non-ionic surfactant 1% TritonX-100 , the experimental study shows the solvation species of Ce+3 extracted into cloud point layer (CPL) have a wavelength for maximum absorb...
متن کامل